Publications

In 2012, NASA’s Curiosity rover landed on Mars to assess its potential as a habitat for past life and investigate the paleoclimate record preserved by sedimentary rocks inside the ~150-kilometer-diameter Gale impact crater. Geological reconstructions from Curiosity rover data have revealed an ancient, habitable lake environment fed by rivers draining into the crater. We synthesize geochemical and mineralogical data from lake-bed mudstones collected during the first 1300 martian solar days of rover operations in Gale. We present evidence for lake redox stratification, established by depth-dependent variations in atmospheric oxidant and dissolved-solute concentrations. Paleoclimate proxy data indicate that a transition from colder to warmer climate conditions is preserved in the stratigraphy. Finally, a late phase of geochemical modification by saline fluids is recognized.

The Mars Science Laboratory Curiosity   rover has been traversing strata at the base of Aeolis Mons (informally known as Mount Sharp) since September 2014. The Murray formation makes up the lowest exposed strata of the Mount Sharp group and is composed primarily of finely laminated lacustrine mudstone intercalated with rare crossbedded sandstone that is prodeltaic or fluvial in origin. We report on the first three drilled samples from the Murray formation, measured in the Pahrump Hills section. Rietveld refinements and FULLPAT full pattern fitting analyses of X-ray diffraction patterns measured by the MSL CheMin instrument provide mineral abundances, refined unit-cell parameters for major phases giving crystal chemistry, and abundances of X-ray amorphous materials. Our results from the samples measured at the Pahrump Hills and previously published results on the Buckskin sample measured from the Marias Pass section stratigraphically above Pahrump Hills show stratigraphic variations in the mineralogy; phyllosilicates, hematite, jarosite, and pyroxene are most abundant at the base of the Pahrump Hills, and crystalline and amorphous silica and magnetite become prevalent higher in the succession. Some trace element abundances measured by APXS also show stratigraphic trends; Zn and Ni are highly enriched with respect to average Mars crust at the base of the Pahrump Hills (by 7.7 and 3.7 times, respectively), and gradually decrease in abundance in stratigraphically higher regions near Marias Pass, where they are depleted with respect to average Mars crust (by more than an order of magnitude in some targets). The Mn stratigraphic trend is analogous to Zn and Ni, however, Mn abundances are close to those of average Mars crust at the base of Pahrump Hills, rather than being enriched, and Mn becomes increasingly depleted moving upsection. Minerals at the base of the Pahrump Hills, in particular jarosite and hematite, as well as enrichments in Zn, Ni, and Mn, are products of acid-sulfate alteration on Earth. We hypothesize that multiple influxes of mildly to moderately acidic pore fluids resulted in diagenesis of the Murray formation and the observed mineralogical and geochemical variations. The preservation of some minerals that are highly susceptible to dissolution at low pH (e.g., mafic minerals and fluorapatite) suggests that acidic events were not long-lived and that fluids may not have been extremely acidic (pH>2). Alternatively, the observed mineralogical variations within the succession may be explained by deposition in lake waters with variable Eh and/or pH, where the lowermost sediments were deposited in an oxidizing, perhaps acidic lake setting, and sediments deposited in the upper Pahrump Hills and Marias Pass were deposited lake waters with lower Eh and higher pH.

Carbon dioxide is an essential atmospheric component in martian climate models that attempt to reconcile a faint young sun with planetwide evidence of liquid water in the Noachian and Early Hesperian. In this study, we use mineral and contextual sedimentary environmental data measured by the Mars Science Laboratory (MSL) Rover Curiosity to estimate the atmospheric partial pressure of CO₂  (P_CO2) coinciding with a long-lived lake system in Gale Crater at ∼3.5 Ga. A reaction–transport model that simulates mineralogy observed within the Sheepbed member at Yellowknife Bay (YKB), by coupling mineral equilibria with carbonate precipitation kinetics and rates of sedimentation, indicates atmospheric P_CO2  levels in the 10s mbar range. At such low P_CO2 levels, existing climate models are unable to warm Hesperian Mars anywhere near the freezing point of water, and other gases are required to raise atmospheric pressure to prevent lake waters from being lost to the atmosphere. Thus, either lacustrine features of Gale formed in a cold environment by a mechanism yet to be determined, or the climate models still lack an essential component that would serve to elevate surface temperatures, at least locally, on Hesperian Mars. Our results also impose restrictions on the potential role of atmospheric CO₂ in inferred warmer conditions and valley network formation of the late Noachian.

Sedimentary rocks are composed of detrital grains derived from source rocks, which are altered by chemical weathering, sorted during transport, and cemented during diagenesis. Fluvio-lacustrine sedimentary rocks of the Bradbury group, observed on the floor of Gale crater by the Curiosity rover during its first 860 Martian solar days, show trends in bulk chemistry that are consistent with sorting of mineral grains during transport. The Bradbury group rocks are uniquely suited for sedimentary provenance analysis because they appear to have experienced negligible cation loss (i.e., open-system chemical weathering) at the scale of the Alpha Particle X-ray Spectrometer bulk chemistry analyses based on low Chemical Index of Alteration values and successful modeling of >90% of the (volatile-free) targets as mixtures of primary igneous minerals. Significant compositional variability between targets is instead correlated to grain-size and textural characteristics of the rocks; the coarsest-grained targets are enriched in Al2O3, SiO2, and Na2O, whereas the finer-grained targets are enriched in mafic components. This is consistent with geochemical and mineralogical modeling of the segregation of coarse-grained plagioclase from finer-grained mafic minerals (e.g., olivine and pyroxenes), which would be expected from hydrodynamic sorting of the detritus from mechanical breakdown of subalkaline plagioclase-phyric basalts. While the presence of a distinctive K₂O-rich stratigraphic interval shows that input from at least one distinctive alkali-feldspar-rich protolith contributed to basin fill, the dominant compositional trends in the Bradbury group are consistent with sorting of detrital minerals during transport from relatively homogeneous plagioclase-phyric basalts.

The Mars Science Laboratory (MSL) Curiosity rover completed a detailed investigation at the Kimberley waypoint within Gale crater from sols 571–634 using its full science instrument payload. From orbital images examined early in the Curiosity mission, the Kimberley region had been identified as a high-priority science target based on its clear stratigraphic relationships in a layered sedimentary sequence that had been exposed by differential erosion. Observations of the stratigraphic sequence at the Kimberley made by Curiosity are consistent with deposition in a prograding, fluvio-deltaic system during the late Noachian to early Hesperian, prior to the existence of most of Mount Sharp. Geochemical and mineralogic analyses suggest that sediment deposition likely took place under cold conditions with relatively low water-to-rock ratios. Based on elevated K2O abundances throughout the Kimberley formation, an alkali feldspar protolith is likely one of several igneous sources from which the sediments were derived. After deposition, the rocks underwent multiple episodes of diagenetic alteration with different aqueous chemistries and redox conditions, as evidenced by the presence of Ca-sulfate veins, Mn-oxide fracture fills, and erosion-resistant nodules. More recently, the Kimberley has been subject to significant aeolian abrasion and removal of sediments to create modern topography that slopes away from Mount Sharp, a process that has continued to the present day.

The history of surface processes on Mars is recorded in the sedimentary rock record. Sedimentary rock layers exposed in Gale Crater on the modern crater floor (Aeolus Palus) and on Mount Sharp (Aeolus Mons), which hosts one of the more complete records of transitions between major mineralogical eras on Mars, have been investigated by the Mars Science Laboratory Curiosity rover since landing in August 2012. This dissertation focuses on the formation and diagenesis of the sedimentary rocks in Gale crater in order to assess the compositional diversity of the volcanic sources around Gale crater, the effects of transport processes on the sediment grains, and the volumes and geochemistry of water that transported and cemented the sediments. The first study uses orbital mapping of a distinctive cemented boxwork layer on Mount Sharp to constrain a minimum volume of groundwater available to form this layer, 1 km above the modern floor of Gale, with implications for the formation of Mount Sharp. The other three studies use Curiosity rover imagery and geochemical data to investigate sedimentary rocks in Aeolus Palus and at the base of Mount Sharp. The second study identifies and describes diagenetic synaeresis cracks in the Sheepbed mudstone, at the lowest elevation in Aeolus Palus, with implications for the duration of water saturation of these lake sediments. The third and fourth studies identify and explain geochemical trends in the fluvio-deltaic Bradbury group, the Murray mudstone formation, and the eolian Stimson sandstone, focusing on geochemical diversity in the source regions for each of these units and how different depositional processes are reflected in the geochemical data. The sedimentary system in Gale crater has changed our understanding of Mars by expanding the known variety of igneous rocks, increasing estimates of the longevity of surface water lakes, and showing that there were once habitable environments on our neighboring planet.

The Curiosity rover has analyzed various detrital sedimentary rocks at Gale Crater, among which fluvial and lacustrine rocks are predominant. Conglomerates correspond both to the coarsest sediments analyzed and the least modified by chemical alteration, enabling us to link their chemistry to that of source rocks on the Gale Crater rims. In this study, we report the results of six conglomerate targets analyzed by Alpha-Particle X-ray Spectrometer and 40 analyzed by ChemCam. The bulk chemistry derived by both instruments suggests two distinct end-members for the conglomerate compositions. The first group (Darwin type) is typical of conglomerates analyzed before sol 540; it has a felsic alkali-rich composition, with a Na2O/K2O > 5. The second group (Kimberley type) is typical of conglomerates analyzed between sols 540 and 670 in the vicinity of the Kimberley waypoint; it has an alkali-rich potassic composition with Na2O/K2O < 2. The variety of chemistry and igneous textures (when identifiable) of individual clasts suggest that each conglomerate type is a mixture of multiple source rocks. Conglomerate compositions are in agreement with most of the felsic alkali-rich float rock compositions analyzed in the hummocky plains. The average composition of conglomerates can be taken as a proxy of the average igneous crust composition at Gale Crater. Differences between the composition of conglomerates and that of finer-grained detrital sediments analyzed by the rover suggest modifications by diagenetic processes (especially for Mg enrichments in fine-grained rocks), physical sorting, and mixing with finer-grained material of different composition.

The landforms of northern Gale crater on Mars expose thick sequences of sedimentary rocks. Based on images obtained by the Curiosity rover, we interpret these outcrops as evidence for past fluvial, deltaic, and lacustrine environments. Degradation of the crater wall and rim probably supplied these sediments, which advanced inward from the wall, infilling both the crater and an internal lake basin to a thickness of at least 75 meters. This intracrater lake system probably existed intermittently for thousands to millions of years, implying a relatively wet climate that supplied moisture to the crater rim and transported sediment via streams into the lake basin. The deposits in Gale crater were then exhumed, probably by wind-driven erosion, creating Aeolis Mons (Mount Sharp).

The ChemCam instrument package on the Curiosity rover was used to characterize distinctive raised ridges in the Sheepbed mudstone, Yellowknife Bay formation, Gale Crater. The multilayered, fracture-filling ridges are more resistant to erosion than the Sheepbed mudstone rock in which they occur. The bulk average composition of the raised ridges is enriched in MgO by 1.2–1.7 times (average of 8.3–11.4 wt %; single-shot maximum of 17.0 wt %) over that of the mudstone. Al2O3 is anticorrelated with MgO, while Li is somewhat enriched where MgO is highest. Some ridges show a variation in composition with different layers on a submillimeter scale. In particular, the McGrath target shows similar high-MgO resistant outer layers and a low-MgO, less resistant inner layer. This is consistent with the interpretation that the raised ridges are isopachous fracture-filling cements with a stratigraphy that likely reveals changes in fluid composition or depositional conditions over time. Overall, the average composition of the raised ridges is close to that of a Mg- and Fe-rich smectite, or saponite, which may also be the main clay mineral constituent of the host mudstone. These analyses provide evidence of diagenesis and aqueous activity in the early postdepositional history of the Yellowknife Bay formation, consistent with a low salinity to brackish fluid at near-neutral or slightly alkaline pH. The fluids that circulated through the fractures likely interacted with the Sheepbed mudstone and (or) other stratigraphically adjacent rock units of basaltic composition and leached Mg from them preferentially.

The Sheepbed member of the Yellowknife Bay formation in Gale crater contains millimeter-scale nodules that represent an array of morphologies unlike those previously observed in sedimentary deposits on Mars. Three types of nodules have been identified in the Sheepbed member in order of decreasing abundance: solid nodules, hollow nodules, and filled nodules, a variant of hollow nodules whose voids have been filled with sulfate minerals. This study uses Mast Camera (Mastcam) and Mars Hand Lens Imager (MAHLI) images from the Mars Science Laboratory Curiosity rover to determine the size, shape, and spatial distribution of the Sheepbed nodules. The Alpha Particle X-Ray Spectrometer (APXS) and ChemCam instruments provide geochemical data to help interpret nodule origins. Based on their physical characteristics, spatial distribution, and composition, the nodules are interpreted as concretions formed during early diagenesis. Several hypotheses are considered for hollow nodule formation including origins as primary or secondary voids. The occurrence of concretions interpreted in the Sheepbed mudstone and in several other sedimentary sequences on Mars suggests that active groundwater systems play an important role in the diagenesis of Martian sedimentary rocks. When concretions are formed during early diagenetic cementation, as interpreted for the Sheepbed nodules, they have the potential to create a taphonomic window favorable for the preservation of Martian organics.

The Sheepbed mudstone, Yellowknife Bay formation, Gale crater, represents an ancient lakebed now exhumed and exposed on the Martian surface. The mudstone has four diagenetic textures, including a suite of early diagenetic nodules, hollow nodules, and raised ridges and later diagenetic light-toned veins that crosscut those features. In this study, we describe the distribution and characteristics of the raised ridges, a network of short spindle-shaped cracks that crosscut bedding, do not form polygonal networks, and contain two to four layers of isopachous, erosion-resistant cement. The cracks have a clustered distribution within the Sheepbed member and transition laterally into concentrations of nodules and hollow nodules, suggesting that these features formed penecontemporaneously. Because of the erosion-resistant nature of the crack fills, their three-dimensional structure can be observed. Cracks that transition from subvertical to subhorizontal orientations suggest that the cracks formed within the sediment rather than at the surface. This observation and comparison to terrestrial analogs indicate that these are syneresis cracks—cracks that formed subaqueously. Syneresis cracks form by salinity changes that cause sediment contraction, mechanical shaking of sediment, or gas production within the sediment. Examination of diagenetic features within the Sheepbed mudstone favors a gas production mechanism, which has been shown to create a variety of diagenetic morphologies comparable to the raised ridges and hollow nodules. The crack morphology and the isopachous, layered cement fill show that the cracks were filled in the phreatic zone and that the Sheepbed mudstone remained fluid saturated after deposition and through early burial and lithification.

While the presence of water on the surface of early Mars is now well known, the volume, distribution, duration, and timing of the liquid water have proven difficult to determine. This study makes use of a distinctive boxwork-rich sedimentary layer on Mount Sharp to map fluid-based cementation from orbital imagery and estimate the minimum volume of water present when this sedimentary interval was formed. The boxwork structures on Mount Sharp are decameter-scale light-toned polygonal ridges that are unique compared to previous observations of Martian fractured terrain because they are parallel-sided ridges with dark central linear depressions. This texture and the sedimentary setting strongly imply that the ridges are early diagenetic features formed in the subsurface phreatic groundwater zone. High-resolution orbital imagery was used to map the volume of light-toned cemented ridges. Based on the cemented volume, a minimum of 5.25 × 105 m3 of cement was deposited within the fractures. Using a brine composition based on observations of other Martian cements and modeling the degree of evaporation, each volume of cement requires 800–6700 pore volumes of water, so the mapped boxwork ridge cements require a minimum of 0.43 km3 of water. This is a significant amount of groundwater that must have been present at the −3620 m level, 1050 m above the current floor of Gale Crater, providing both a new constraint on the possible origins of Mount Sharp and a possible future science target for the Curiosity rover where large volumes of water were present, and early mineralization could have preserved a once-habitable environment.

The Curiosity rover discovered fine-grained sedimentary rocks, inferred to represent an ancient lake, preserve evidence of an environment that would have been suited to support a Martian biosphere founded on chemolithoautotrophy. This aqueous environment was characterized by neutral pH, low salinity, and variable redox states of both iron and sulfur species. C, H, O, S, N, and P were measured directly as key biogenic elements, and by inference N and P are assumed to have been available. The environment likely had a minimum duration of hundreds to tens of thousands of years. These results highlight the biological viability of fluvial-lacustrine environments in the post-Noachian history of Mars.

Uzboi Vallis (centered at ∼28°S, 323°E) is ∼400 km long and comprises the southernmost segment of the northward-draining Uzboi–Ladon–Morava (ULM) meso-scale outflow system that emerges from Argyre basin. Bond and Holden craters blocked the valley to the south and north, respectively, forming a Late Noachian-to-Hesperian paleolake basin that exceeded 4000 km3. Limited CRISM data suggest lake deposits in Uzboi and underlying basin floor incorporate relatively more Mg-clays and more Fe-clays, respectively. The short-lived lake overflowed and breached Holden crater’s rim at an elevation of −350 m and rapidly drained into the crater. Fan deltas in Holden extend 25 km from the breach and incorporate meter-sized blocks, and longitudinal grooves along the Uzboi basin floor are hundreds of meters long and average 60 m wide, suggesting high-discharge drainage of the lake. Precipitation-derived runoff rather than regional groundwater or overflow from Argyre dominated contributions to the Uzboi lake, although the failure of most tributaries to respond to a lowering of base level indicates their incision largely ended when the lake drained. The Uzboi lake may have coincided with alluvial and/or lacustrine activity in Holden, Eberswalde, and other craters in southern Margaritifer Terra, where fluvial/lacustrine activity may have required widespread, synoptic precipitation (rain or snow), perhaps associated with an ephemeral, global hydrologic system during the Late Noachian into the Hesperian on Mars.

This paper summarizes Spirit Rover operations in the Columbia Hills, Gusev crater, from sol 1410 (start of the third winter campaign) to sol 2169 (when extrication attempts from Troy stopped to winterize the vehicle) and provides an overview of key scientific results. The third winter campaign took advantage of parking on the northern slope of Home Plate to tilt the vehicle to track the sun and thus survive the winter season. With the onset of the spring season, Spirit began circumnavigating Home Plate on the way to volcanic constructs located to the south. Silica-rich nodular rocks were discovered in the valley to the north of Home Plate. The inoperative right front wheel drive actuator made climbing soil-covered slopes problematical and led to high slip conditions and extensive excavation of subsurface soils. This situation led to embedding of Spirit on the side of a shallow, 8 m wide crater in Troy, located in the valley to the west of Home Plate. Examination of the materials exposed during embedding showed that Spirit broke through a thin sulfate-rich soil crust and became embedded in an underlying mix of sulfate and basaltic sands. The nature of the crust is consistent with dissolution and precipitation in the presence of soil water within a few centimeters of the surface. The observation that sulfate-rich deposits in Troy and elsewhere in the Columbia Hills are just beneath the surface implies that these processes have operated on a continuing basis on Mars as landforms have been shaped by erosion and deposition.

Decades of speculation about a warmer, wetter Mars climate in the planet’s first billion years postulate a denser CO2-rich atmosphere than at present. Such an atmosphere should have led to the formation of outcrops rich in carbonate minerals, for which evidence has been sparse. Using the Mars Exploration Rover Spirit, we have now identified outcrops rich in magnesium-iron carbonate (16 to 34 weight percent) in the Columbia Hills of Gusev crater. Its composition approximates the average composition of the carbonate globules in martian meteorite ALH 84001. The Gusev carbonate probably precipitated from carbonate-bearing solutions under hydrothermal conditions at near-neutral pH in association with volcanic activity during the Noachian era.

The Mars Phoenix Lander was equipped with a 2.4 m Robotic Arm (RA) with an Icy Soil Acquisition Device capable of excavating trenches in soil deposits, grooming hard icy soil surfaces with a scraper blade, and acquiring icy soil samples using a rasp tool. A camera capable of imaging the scoop interior and a thermal and electrical conductivity probe were also included on the RA. A dozen trench complexes were excavated at the northern plains landing site and 31 samples (including water-ice-bearing soils) were acquired for delivery to instruments on the Lander during the 152 sol mission. Deliveries included sprinkling material from several centimeters height to break up cloddy soils on impact with instrument portals. Excavations were done on the side of the Humpty Dumpty and the top of the Wonderland polygons, and in nearby troughs. Resistive forces encountered during backhoe operations show that soils above the 3–5 cm deep icy soil interfaces are stronger with increasing depth. Further, soils are similar in appearance and properties to the weakly cohesive crusty and cloddy soils imaged and excavated by the Viking Lander 2, which also landed on the northern plains. Adsorbed H2O is inferred to be responsible for the variable nature and cohesive strength of the soils. Backhoe blade chatter marks on excavated icy soil surfaces, combined with rasp motor currents, are consistent with laboratory experiments using grain-supported icy soil deposits, as is the relatively rapid decrease in icy soil strength over time as the ice sublimated on Mars.